MC-ICP-MS高精度Cu、Zn同位素测试技术   总被引：4，自引：1，他引：3  

侯可军  李延河  田有荣  秦燕  谢桂青 《矿床地质》2008,27(6):774-781

过渡族元素同位素是国际上同位素地球化学研究的热点。测试技术的限制是制约过渡元素同位素研究发展的关键。笔者利用Neptune型多接收等离子质谱(MC-ICP-MS),采用Cu、Zn互为内标的方法对仪器的质量歧视进行了校正,对基质效应和测试方法的重现性进行了检验,建立了高精度的Cu、Zn同位素测试技术。在5个月内对实验室标准IMRCu和IMRZn进行了测量,结果分别为δ65CuNIST976=(0.34±0.08)‰(2SD,n=32),δ66ZnJMCZn=(-9.64±0.05)‰(2SD,n=26),δ67ZnJMCZn=(-14.37±0.16)‰(2SD,n=26),δ68ZnJMCZn=(-19.01±0.08)‰(2SD,n=26),分析精度达到国际同类实验室先进水平。对Cu、Zn同位素参考物质进行了对比测量,分析结果与报道值在误差范围内完全一致。  相似文献   

A study of the seismic response of the city of Benevento (Southern Italy) through a combined analysis of seismological and geological data   总被引：1，自引：0，他引：1  

G. Di Giulio  L. Improta  G. Calderoni  A. Rovelli 《Engineering Geology》2008,97(3-4):146-170

A previous analysis [Improta, L., G. Di Giulio, and A. Rovelli (2005). Variations of local seismic response in Benevento (Southern Italy) using earthquakes and ambient noise recordings, J. Seism. 9, 191–210.] of small magnitude earthquakes recorded at 12 sites within the city of Benevento has stressed the significant role played by near-surface geology in causing variability of the ground motion. In this paper, we extend the study of the seismic response from 12 sites to the entire urban area. Based on inferences from the comparison at the 12 sites between earthquake and ambient vibration results, we have collected ambient noise at about 100 sites within the city, intensifying measurements across the main shallow geological variations. We use borehole data to interpret ambient noise H/V spectral ratios in terms of near-surface geology comparing H/V curves to theoretical transfer functions of 1D models along five well-constrained profiles.

On the basis of geological, geotechnical, and seismic data, we identify three main typologies of seismic response in the city. Each type of response is associated to zones sharing common soil conditions and similar soil classes according to building codes for seismic design. Moreover, we find that the spatial variation of the seismic response in the ancient town area is consistent with the damage pattern produced by a very destructive, well-documented historical earthquake that struck the city in 1688, causing MCS intensity of IX–X in Benevento.

Finally, we use ground motions recorded during the experiment by Improta et al. [Improta, L., G. Di Giulio, and A. Rovelli (2005). Variations of local seismic response in Benevento (Southern Italy) using earthquakes and ambient noise recordings, J. Seism. 9, 191–210.] to generate synthetic seismograms of moderate to strong (Mw 5.7, Molise 2002 and Ms 6.9, 1980 Irpinia) earthquakes. We calibrate the random summation technique by Ordaz et al. [Ordaz, M., J. Arboleda, and S.K. Singh (1995). A scheme of random summation of an Empirical Green's Function to estimate ground motions for future large earthquakes, Bull. Seism. Soc. Am. 85, 1635–1647.] using recordings of these earthquakes available in Benevento. After a satisfactory fit between observed and synthetic seismograms, we compute response spectra at different sites and speculate on effects of the geology class at large level of shaking, including soil nonlinearity. We find that large discrepancies from design spectra prescribed by seismic codes can occur for a wide sector of Benevento, especially for periods < 0.5 s.  相似文献   

Site effects modelling applied to the slope affected by the Suusamyr earthquake (Kyrgyzstan, 1992)     

C. Bourdeau  H.-B. Havenith   《Engineering Geology》2008,97(3-4):126-145

In 1992, a large magnitude earthquake (Ms = 7.3) hit the northern part of the Kyrgyz Tien Shan range where it triggered rockslides and many debris slides or flows. One of these mass movements occurred on the Chet–Korumdy ridge located in the Suusamyr Basin. It consists of a multi-rotational debris slump in its upper part that turned into a debris flow in its lower part. Involving arenitic material overlying silty clays, it has a volume of about 0.5 to 1.10⁶ m³, a maximum thickness of 40 m and a run-out of 200 m. The field observations and measurements carried out on this slope suggest that local amplification effects could have contributed to the initiation of the seismic failure. To test this hypothesis in the lack of instrumental evidence of local ground-motion recordings, we conducted a sensitivity study of site effects based on a numerical analysis in the visco-elastic domain with a two-dimensional finite difference code. Varying the topography and the geology of the investigated slope, topographic site effects are found to be less important than geological site effects which are controlled by the contrast of impedance between the surface materials and the bedrock. The geometry of the low-velocity surface layer has also an influence on site effects, which is often difficult to be distinguished from pure topographic effects. Considering all modelling results, we conclude that site amplifications alone cannot have triggered the Suusamyr landslide during the 1992 earthquake. The static slope stability analyses done in previous studies revealed that the Suusamyr failure neither can have a purely static origin. Even if the water table is very high within the arenite layer, only a minor failure develops in the lower part of the slope. Therefore, we believe that the triggering of the Suusamyr landslide is a consequence of pore pressure build up in areas characterized by significant ground-motion amplifications.  相似文献   

Neo-deterministic definition of seismic input for residential seismically isolated buildings   总被引：1，自引：1，他引：0  

Elisa Zuccolo  Franco Vaccari  Antonella Peresan  Alberto Dusi  Alessandro Martelli  Giuliano F. Panza   《Engineering Geology》2008,101(3-4):89-95

This paper deals with the neo-deterministic definition of the seismic input in the municipality of Nimis (Italy), aimed at the design of residential seismically isolated buildings. The seismic input is defined by the computation of realistic synthetic seismograms considering different levels of detail for the earthquake source, both for a bedrock model and taking into account the specific site conditions. The horizontal response spectrum, calculated in the centre of the municipality by modelling the most dangerous source, advises against the construction of a building with a fixed base, but it is compatible with the seismic isolation, and it has been, therefore, used for the design of a residential seismically isolated building. The maximum displacement for the isolation system has been estimated about 17 cm, a value much lower than that provided by the code design response spectrum (28 cm). The importance of the realistic modelling, which permits the generalization of empirical observations by means of, physically sound, theoretical considerations, is evident, as it allows for the optimisation of the structural design with respect to the site of interest.  相似文献   

Environmental effect and genetic influence: a regional cancer predisposition survey in the Zonguldak region of Northwest Turkey     

Selahattin Kadir  A. Piril Önen-Hall  S. Nihal Aydin  Cengiz Yakicier  Nurten Akarsu  Murat Tuncer 《Environmental Geology》2008,54(2):391-409

The Cretaceous-Eocene volcano-sedimentary units of the Zonguldak region of the western Black Sea consist of subalkaline andesite and tuff, and sandstone dominated by smectite, kaolinite, accessory chlorite, illite, mordenite, and analcime associated with feldspar, quartz, opal-CT, amphibole, and calcite. Kaolinization, chloritization, sericitization, albitization, Fe–Ti-oxidation, and the presence of zeolite, epidote, and illite in andesitic rocks and tuffaceous materials developed as a result of the degradation of a glass shards matrix, enclosed feldspar, and clinopyroxene-type phenocrysts, due to alteration processes. The association of feldspar and glass with smectite and kaolinite, and the suborientation of feldspar-edged, subparallel kaolinite plates to fracture axes may exhibit an authigenic smectite or kaolinite. Increased alteration degree upward in which Al, Fe, and Ti are gained, and Si, Na, K, and Ca are depleted, is due to the alteration following possible diagenesis and hydrothermal activities. Micromorphologically, fibrous mordenite in the altered units and the presence of needle-type chrysotile in the residential buildings in which cancer cases lived were detected. In addition, the segregation pattern of cancer susceptibility in the region strongly suggested an environmental effect and a genetic influence on the increased cancer incidence in the region. The most likely diagnosis was Li-Fraumeni syndrome, which is one of the hereditary cancer predisposition syndromes; however, no mutations were observed in the p53 gene, which is the major cause of Li-Fraumeni syndrome. The micromorphology observed in the altered units in which cancer cases were detected may have a role in the expression of an unidentified gene, but does not explain alone the occurrence of cancer as a primary cause in the region.  相似文献   

正规矩阵选取半参数灰色模型改进的预测建模     

周敏  周世健  王奉伟 《测绘科学》2016,41(8):152-155,164

正规矩阵是对模型误差补偿性的直接表达,时间序列法用一阶差分方程和二阶差分方程计算得到不同的正规矩阵。针对传统GM(1,1)模型没有考虑模型误差,而数据处理过程中所建立的数学模型与客观现实并不一致的问题,该文提出建立顾及模型误差的半参数模型的GM(1,1)模型。对由传统半参数模型得到的正规矩阵采取一阶差分法进行改进,并通过算例证实了改进正规矩阵的半参数模型的GM(1,1)预测精度更高。  相似文献   

群组目标空间方向关系形式化描述模型   总被引：1，自引：0，他引：1  

禄小敏  闫浩文  王中辉  甘治国 《测绘科学》2016,41(8):71-75

针对目前群组目标空间方向关系模型在描述方向关系方面存在的不精确及复杂性等问题,该文提出一种形式化描述模型。该模型采用"剥皮"法计算得到源目标群的边界多边形,较好地顾及了空间形状及分布范围对方向关系的影响;并通过方向关系矩阵模型计算源目标群的边界多边形与各方向区域之间的交,借助矩阵形式化描述源目标群相对于参考目标群的空间方向关系。实验结果表明,该模型较好地克服了现有方法中存在的缺陷,能够准确判断地理空间中两个群组目标之间的空间方向关系。  相似文献   

一种基于无人机位姿信息的航拍图像拼接方法   总被引：1，自引：0，他引：1  

程争刚  张利 《测绘学报》2016,45(6):698-705

针对现有航拍图像拼接方法处理速度较慢的问题,提出一种基于无人机位姿信息的快速拼接方法。首先从机载GPS和惯性导航单元获得无人机航拍时的坐标和姿态角,根据每一幅航拍图像对应的无人机坐标和姿态角计算它们之间的单应变换矩阵,实现航拍图像之间的快速配准。然后通过单应变换矩阵的运算得到拼接图像之间的配准,最后完成多幅图像的拼接得到整个区域的全景图。试验结果证明该方法快速有效。  相似文献   

Quaternion-EKF的多源传感器联合定向算法     

赵文晔  高井祥  刘昶 《测绘科学技术学报》2016,(3):247-251

针对磁力计易受干扰和陀螺仪易漂移的问题,使用扩展卡尔曼滤波EKF(Extended Kalman Filter)融合多源传感器进行定向。利用基于四元数的EKF,在当地磁场和重力加速度的基础上融合加速度计、陀螺仪和磁力计观测信息,并通过自适应算法构建过程噪声向量和观测噪声向量的协方差矩阵以解决载体运动和周围磁场干扰对重力和地磁场观测值的影响。实验结果表明,该算法可以有效地减弱陀螺仪漂移和磁场对定向的干扰,获得更加精确和稳定的航向角信息。  相似文献   

On the determination of the mesh size for numerical simulations of shock wave propagation in near field underwater explosion     

《Applied Ocean Research》2016

It is well known that the accuracy of mesh-based numerical simulations of underwater explosion strongly relies on the mesh size adopted in the analyses. Although a numerical analysis of underwater explosion can be performed with enough accuracy by using considerably fine meshes, such fine meshes may lead to substantially increase in the CPU time and the usage of computer memory. Thus, how to determine a suitable mesh size in numerical simulations is always a problem confronted when attempting to study the shock wave propagation resulting from underwater explosion and the subsequent response of structures. Considering that there is currently no universally accepted method for resolving this problem, this paper aims to propose a simple method to determine the mesh size for numerical simulations of near field underwater explosion. To this end, the mesh size effects on the shock wave propagation of underwater explosion are carefully investigated for different charge weights, through which the correlation between mesh sizes and charge weights is identified. Based on the numerical study, a dimensionless variable (λ), defined as the ratio of the radius of charge to the side length of element, is introduced to be the criterion for determining the mesh size in simulations. It is interesting to note that the presented method is suitable for various charge weights. By using the proposed meshing rule, adequate balance between solution accuracy and computational efficiency can be achieved for different blast scenarios in numerical simulations of underwater explosion.  相似文献